Hi
Common problem,
Try using a sharp point through the hole for the screw that holds chamber in, tap it gently, if you are precise, you can angle the point to slowly move it out of the barrel.
One thing that can happen is there is a small point of contact between the extractor and the barrel/chamber edge, this can become "burred" over and stop the chamber coming out smoothly, if this is the case remove the burr with dremmel or such like.
On the positive side the point through the hole always works for me:)